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Uranium 'sandwich' molecule uranocenium isolated after 50-year hunt

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Uranium 'sandwich' molecule uranocenium isolated after 50-year hunt

A closer look at “Uranium 'sandwich' molecule uranocenium isolated after 50-year hunt”, exactly as the source publishes it. Researchers from The University of Manchester and Lancaster University have isolated uranocenium, a positively charged uranium molecule that has eluded chemists for over 50 years. The breakthrough, published in Nature Communications, builds on the landmark compound uranocene, first reported in 1968, and provides the first direct experimental evidence of its cationic form. Uranocenium is a 'sandwich' molecule, with a uranium ion nestled between two cyclooctatetraene rings.

Its stability and bonding behavior challenge conventional assumptions about heavy-element chemistry, offering fresh insights into how actinides interact with organic ligands. The team used advanced synthetic and spectroscopic techniques to confirm the molecule's structure and electronic properties. This discovery matters because it could inform the design of new materials for nuclear waste management, catalysis, and quantum technologies. For the complete material, the listing points back to the source inside the network.

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